Neutralization is a chemical reaction, also called a water forming reaction, in which an acid and a base or alkali (soluble base) react and produce a salt and water(H2O). In other words, it can be said that neutralization is the combination of hydrogen ions H+ and hydroxide ions OH− (or oxide ions O2−) to form water molecule H2O. In the process, a salt is formed. In the process of neutralization a proton (usually hydrogen) is transferred. An acid is a proton donor, while a base is a proton receiver. H2O can act as either an acid or a base, depending on whether it comes in contact with an acid or a base (it takes the opposite form) Neutralization is generally exothermic, meaning it produces heat. One example of an endothermic neutralization is that of baking soda and vinegar (or other weak acids)
Most generally, the following occurs:
- acid + base → salt + water
- hydrochloric acid + sodium hydroxide → sodium chloride + water
- HCl(aq) + NaOH(aq) → NaCl(aq) + H2O(l)
Since the HCl and NaOH dissociate into ions in solution, the ionic equation is:
- H+(aq) + Cl−(aq) + Na+(aq) + OH−(aq) → Na+(aq) + Cl−(aq) + H2O(l)
And since the sodium and chloride ions are just spectator ions not involved in the reaction, the net equation becomes:
- H+(aq) + OH−(aq) → H2O(l) : ΔrH = −55.90 kJ mol−1
This illustrates why neutralization reactions are also referred to as water forming reactions. Of course the sodium and chloride ions are still in solution so the result is pH neutral salt water.
Therefore we can conclude -
acid + metal oxide = metal salt + water
acid + metal hydroxide = metal salt + water
acid + metal carbonate = metal salt + water + carbon dioxide
acid + metal hydrogen carbonate = metal salt + water + carbon dioxide
acid + ammonia = ammonia salt + water
Chemical titration methods are used for analyzing acids or bases to determine the unknown concentration. A pH meter can be used to determine the point of neutralization or a pH indicator such as UI (universal indicator) which shows the point of neutralization by a distinct color change can be used. Simple stoichiometric calculations with the known volume of the unknown and the known volume and molarity of the added chemical gives the molarity of the unknown.
Neutralization can also be used to reduce the pain of insect and plant stings. Bee stings can be neutralized with alkalis and wasps with acids. Nettle stings can be neutralized with alkalis like the one found in dock leaves.
In wastewater treatment, chemical neutralization methods are often applied to reduce the damage that an effluent may cause upon release to the environment. For pH control, popular chemicals include Calcium Carbonate, Calcium Oxide, Magnesium Hydroxide, and Sodium Bicarbonate. The selection of an appropriate neutralization chemical depends on the particular application.
Equal amounts (numbers of moles) of acid and base are needed for neutralization reactions between strong acids and strong bases. Use the formula:
a × [A] × Va = b × [B] × Vb
where a is the number of acidic hydrogens and b is the constant that tells you how many H3O+ ions the base can accept. [A] denotes the concentration of acid and [B], the concentration of base. Va is the volume of acid and Vb is the volume of base.
Metcalf & Eddy. Wastewater Engineering, Treatment and Reuse. 4th ed. New York: McGraw-Hill, 2003. 526-532.