Acetylene tetrabromide

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Acetylene tetrabromide
Seletal formula of tetrabromoethane
Stereo, skeletal formula of tetrabromoethane with all explicit hydrogens added
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Names
IUPAC name
1,1,2,2-Tetrabromoethane[1]
Other names
Identifiers
3D model (JSmol)
ChemSpider
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MeSH 1,1,2,2-tetrabromoethane
Properties
C2H2Br4
Molar mass 345.65 g·mol−1
Hazards
Related compounds
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Editor-In-Chief: C. Michael Gibson, M.S., M.D. [1]

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Overview

Tetrabromoethane (TBE) is a halogenated hydrocarbon, chemical formula C2H2Br4. Although three bromine atoms may bind to one of the carbon atoms creating 1,1,1,2-tetrabromoethane this is not thermodynamically favorable, so in practice tetrabromoethane is equal to 1,1,2,2-tetrabromoethane, where each carbon atom binds two bromine atoms.

It has an unusually high density for an organic compound, near 3 g/mL, due largely to the four bromine atoms.[2] TBE is a liquid at room temperature, and is used to separate mineral ores from its supporting rock by means of preferential flotation. Sand, limestone, dolomite, and other types of rock material will float on TBE, while minerals such as sphalerite, galena and pyrite will sink. A related compound, bromoform, is also sometimes used in these applications, however, TBE is more practical because of its wider liquid range and lower vapor pressure.[2] Acute TBE poisoning has been known to occur.[3]

References

  1. "1,1,2,2-tetrabromoethane - Compound Summary". PubChem Compound. USA: National Center for Biotechnology Information. 26 March 2005. Identifiction. Retrieved 20 June 2012.
  2. 2.0 2.1 Organic based heavy liquids, heavyliquids.com
  3. A B van Haaften (1969). "Acute tetrabromoethane (acetylene tetrabromide) intoxication in man". American Industrial Hygiene Association. 30 (3): 251–256. doi:10.1080/0002889698506042.


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